Have questions or comments? 3 Chemical and Physical Properties Expand this section. 1 Structures Expand this section. ANTIMONY IN DRINKING-WATER 2 1.5 Environmental fate The emission of antimony into the human environment … Construction of 2D Antimony(III) Selenide Nanosheets for Highly Efficient Photonic Cancer Theranostics. Antimony(III) oxide is a useful catalyst in the production of polyethylene terephthalate (PET plastic) and the vulcanization of rubber. Im 17. Yadan Zhou. (2008). Antimony Trioxide Nanopowder. CHEBI:30302 [DBID] UNII:069647RPT5 [DBID] UNII-069647RPT5 [DBID] Predicted - ACD/Labs; Predicted - EPISuite; Predicted - ChemAxon; Predicted data is generated using the ACD/Labs … Antimon(III)-fluorid wird als mäßig aktives Fluorierungsmittel, bevorzugt für niedrig schmelzende Fluoride, verwendet. Im Periodensystem steht es in der 5. Not very active, but reacts with oxygen, sulfur and chlorine at high temperatures. In der stabilen Modifikation ist es ein silberglänzendes und sprödes Halbmetall. Missed the LibreFest? Antimon wurde in Form seiner Verbindungen schon in der Bronzezeit als Zuschlag zu Kupfer verwendet, um Bronze herzustellen (Funde von Velem-St. Vid in Ungarn) und auch im Altertum genutzt. Chemical Formula: Sb+ 3. click here for details. School of Mineral Processing and Bio‐engineering, … Characteristic Reactions of Antimony Ions (Sb³⁺) Last updated; Save as PDF Page ID 97261; Contributed by James P. Birk; Professor Emeritus (Chemistry) at Arizona State University; Chloride Ion: Aqueous Ammonia: Sodium Hydroxide; Hydrogen Sulfide; Water; Reducing Agents; No Reaction; Most common oxidation states: +3, +5; M.P. Synonym: Antimony trichloride. The sulphuric acid reaction produces SO 2. Antimony Black. Molecular Weight: 531.71. Antimony(III) Cite. Antimony(III) oxide, CP. The electron configuration for antimony is 1s 2 2s 2 2p 6 3s 2 3p 6 4s 2 3d 10 4p 6 5s 2 4d 10 5p 3. IUPAC Name: antimony(3+) CAS Number: 23713-48-6 . 2005-03-27. 2015-12-24. Chenyang Zhang. Ganz siche… Canadian Metallurgical Quarterly: Vol. Safety. More... Molecular Weight: 291.52 g/mol. 630º; B.P. Component Compounds: CID 5354495 (Antimony) CID 783 (Hydrogen) Dates: Modify . Search for more papers by this author . Jahrhundert ging der Name Antimon als Bezeichnung auf das Metall über. Abstract Antimony, a pollutant of priority interest by United States Environment Protection Agency (USEPA) and Europe Union (EU), is detected in soil and water with elevated concentration due to its extensive use in a variety of industries. Antimony(III) oxide has suspected carcinogenic potential for humans. ≥99.95% trace metals basis. Antimony has been extensively used in lead alloys, battery grids, bearing metal, cable sheathing, plumber’s solder, pewter, ammunition, sheet, and pipe. The noble gas electron configuration is: The... See full answer below. Materials that exhibit large and rapid switching of their optical properties in the visible spectrum hold the key to color-changing devices. Under moderately acidic conditions, \(\ce{H2S}\) precipitates red \(\ce{Sb2S3}\). It also is used in the production of ruby-colored glass and in plastics as a flame retardant. Antimony(III) sulfate. 337374. Choose from 21 different sets of term:sb = antimony (iii) ion flashcards on Quizlet. Tweet. The LibreTexts libraries are Powered by MindTouch® and are supported by the Department of Education Open Textbook Pilot Project, the UC Davis Office of the Provost, the UC Davis Library, the California State University Affordable Learning Solutions Program, and Merlot. Es gehört zur Stoffklasse der Oxide. 3, pp. CopyCopied, CSID:94667, http://www.chemspider.com/Chemical-Structure.94667.html (accessed 13:28, Jan 6, 2021) Antimony, Sb 3+ Most common oxidation states: +3, +5 M.P. 2020-11-29. State Key Laboratory of Powder Metallurgy, College of Chemistry and Chemical Engineering, Central South University, Changsha, 410083 China . Search for more papers by this author. We also acknowledge previous National Science Foundation support under grant numbers 1246120, 1525057, and 1413739. APT (tartar emetic) has been used to induce vomiting in poisoning cases, and antimony compounds such as piperazine antimony tartrate were used as drugs against bilharzia. Solutions of antimony(III) chloride in \(\ce{HCl}\) react when added to excess water to form the basic, white, insoluble salt \(\ce{SbOCl}\). More... Antimony (3+) is a monoatomic trication and an elemental antimony. Antimony(III) Sulfide Thin Films as a Photoanode Material in Photocatalytic Water Splitting | ACS Applied Materials & Interfaces For the first time, we present exploratory investigations on the performance of thermally evaporated Sb2S3 thin film photoanodes for solar-assisted water-splitting applications. \[\ce{Sb2S3(s) + 3S2^{-}­(aq) <=> 2SbS33­(aq)}\], \[\ce{Sb2S3(s) + 6H^{+}(aq) + 8Cl­^{-}(aq) <=> 2SbCl4^{2-}­(aq) + 3H2S(aq)}\]. antimony(iii) 23713-48-6 [RN] Antimony [Wiki] ANTIMONY (III) ION. Some specialty pigments contain antimony. Sigma-Aldrich. Außerdem dient es als Beizmittel zum Färben und wird bei der Herstellung von Keramik verwendet. 1380 o. Density 6.69 g/cm 3. SDS; Antimony(III) sulfide. 2020-12-26. and are physiologically tolerated more than trivalent antimony (antimony(III)) compounds (Winship, 1987). The known anti- mony(III) based ion exchangers are antimony(llI) arsenate, antimony(III) molybdate", antimony(llI) selenite and antimony(III) tungstate", But a hetero- polyacid ion exchanger based on annmonytlll) has not yet been reported. For more information contact us at info@libretexts.org or check out our status page at https://status.libretexts.org. In the presence of \(\ce{HCl}\), either aluminum or iron will reduce \(\ce{Sb^{3+}}\) to \(\ce{Sb}\) metal, which will be deposited as black particles. More by Yadan Zhou, Wei Feng* Wei Feng . InChI=1S/Sb/q+3 Die von Jöns Jakob Berzelius benutzte Abkürzung Sb wird noch heute als Elementsymbol genutzt. This sulfide is soluble in solutions of hot \(\ce{NaOH}\) which contain excess sulfide ion and in hot, concentrated (12 M) \(\ce{HCl}\). 2 Names and Identifiers Expand this … WEB … 1 Product Result | Match Criteria: Product Name, Property, Description Linear Formula: Sb 2 (SO 4) 3. 19F and 1Н NMR methods were used to study ion mobility in M6Sb4(SO4)3F12 (M = Rb, Cs, NH4) and (NH4)2Sb(SO4)F3 complex antimony(III) sulfate fluorides with alkali cations and ammonium. Sb(III) reacts with aqueous ammonia to precipitate white \(\ce{Sb(OH)3}\). 1 Structures Expand this section. A study of the ion exchange removal of antimony(III) and antimony(V) from copper electrolytes. 2 Names and Identifiers Expand this section. Heavy metal ions such as Sb(III) are toxic and carcinogenic at relatively low concentrations. 10783 ≥95.0% ; Sigma-Aldrich pricing. Create . State Key Laboratory of Powder Metallurgy, College of Chemistry and Chemical Engineering, Central South University, Changsha, 410083 China. CopyCopied, Validated by Experts, Validated by Users, Non-Validated, Removed by Users, Predicted data is generated using the ACD/Labs Percepta Platform - PhysChem Module, Predicted data is generated using the US Environmental Protection Agency’s EPISuite™, Click to predict properties on the Chemicalize site, For medical information relating to Covid-19, please consult the, ACD/Labs Percepta Platform - PhysChem Module, US Environmental Protection Agency’s EPISuite™, Compounds with the same molecular formula, Search Google for structures with same skeleton. pricing. Antimony(III) oxide is an opacifying agent for glasses, ceramics and enamels. CopyCopied, FAWGZAFXDJGWBB-UHFFFAOYSA-N Antimony (3+) Please visit the Antimony element page for information specific to the chemical element of the periodic table. ANTIMONY CATION (3+) More... +)) Validated by Experts, Validated by Users, Non-Validated, Removed by Users. 630 o. B.P. Characteristics: Brittle, silvery. Molecular Formula: H 2 Sb: Synonyms: Antimony(III) Molecular Weight: 123.78 g/mol. 4 Spectral Information Expand this section. Structural Diversity in Cesium Bismuth Halide Nanocrystals. Antimon [antiˈmoːn] (von lateinisch Antimonium, vermutlich von arabisch al-ithmîd(un) (ithmid / إثمد / iṯmid, Antimonsulfid bzw. Dual Functions of Potassium Antimony(III)‐Tartrate in Tuning Antimony/Carbon Composites for Long‐Life Na‐Ion Batteries. Hauptgruppe, bzw. Linear Formula: SbCl3. Chenyang Zhang. Unless otherwise noted, LibreTexts content is licensed by CC BY-NC-SA 3.0. Among several industrial applications of antimony compounds, antimony trioxide is largely employed in the production of glassware and ceramics. Choose from 97 different sets of term:sb 3 = antimony (iii) ion flashcards on Quizlet. PubChem CID: 102060556: Structure: Find Similar Structures. Halides of ns2 metal ions have recently regained broad research interest as bright narrowband and broadband emitters. Antimon(III)-fluorid ist für den Menschen giftig. Sb(III) is particularly appealing for its oxidative stability (compared to Ge2+ and Sn2+) and low toxicity (compared to Pb2+). The toxicity of antimony(III) ion is 10 times higher than that of antimony(V) ion, and antimony(III) has been shown to cause lung cancer (Garbooe et al., 1997). Sodium hydroxide also precipitates \(\ce{Sb(OH)3}\), which is amphoteric and dissolves in an excess of hydroxide and in acids. 47, No. Tianjing Wu. 6 Chemical Vendors. Main group metal ions antimony (III) and bismuth (III) with external electron shell of s 2 configuration belong to the so-called mercury-like ions. Antimony is dissolved in hot concentrated sulphuric acid, H 2 SO 4, or nitric acid, HNO 3, forming Sb(III) solutions. Stibnit)) ist ein chemisches Element mit dem Elementsymbol Sb (von lateinisch Stibium (Grau-)Spießglanz) und der Ordnungszahl 51. Create . Dates: Modify . Antimony does not react with hydrochloric acid in the absence of oxygen. It is manufactured for use in safety matches, military ammunition, explosives and fireworks. Characteristic reactions of Sb 3+: (Sb(III) is the more stable oxidation state.) Learn term:sb = antimony (iii) ion with free interactive flashcards. The types of ionic mobility in these compounds were identified at 150–470 K. 15. Characteristic Reactions of Antimony Ions (Sb³⁺), [ "article:topic", "authorname:jbirk", "Antimony", "showtoc:no" ], https://chem.libretexts.org/@app/auth/2/login?returnto=https%3A%2F%2Fchem.libretexts.org%2FBookshelves%2FAnalytical_Chemistry%2FSupplemental_Modules_(Analytical_Chemistry)%2FQualitative_Analysis%2FCharacteristic_Reactions_of_Select_Metal_Ions%2FAntimony%252C_Sb3, Characteristic Reactions of Select Metal Ions, Characteristic Reactions of Aluminum Ions (Al³⁺), information contact us at info@libretexts.org, status page at https://status.libretexts.org, Characteristic reactions of \(\ce{Sb^{3+}}\): (Sb(III) is the more stable oxidation state. Dual Functions of Potassium Antimony(III)‐Tartrate in Tuning Antimony/Carbon Composites for Long‐Life Na‐Ion Batteries Abstract Antimony holds a high‐specific capacity as a promising anode material for Na‐ion batteries (SIBs) and much research is focused on solving the poor cycling stability issue associated with its large volume expansion during alloying/dealloying processes. This article is cited by 83 publications. Department of Ultrasound, Sir Run Run Shaw Hospital, Zhejiang University School of Medicine, Hangzhou 310016, P. R. China. Watch the recordings here on Youtube! ). Sicherheitshinweise. Contents. School of Mineral Processing and Bio‐engineering, … Antimony trisulfide (Sb2S3) is a chalcogenide material that exhibits large refractive index changes of ~1 between crystalline and amorphous states. Sidney E. Creutz, Hongbin Liu, Mitchell E. Kaiser, Xiaosong Li, Daniel R. Gamelin. Yadan Zhou. Learn term:sb 3 = antimony (iii) ion with free interactive flashcards. CAS Number: 10025-91-9. Share. No reaction observable, but will be present as \(\ce{SbCl4­}\). Resources Search for: ANTIMONY (III) ION . 5 Related Records Expand this section. Periode und der 5. Legal. Molecular Weight: 228.12. Antimony (V) ion - chemical information, properties, structures, articles, patents and more chemical data. 307-316. Chloride Ion: Die koptische Bezeichnung für das Schminkpuder Antimonsulfid ging über das Griechische in das Lateinische stibium über. CAS Number: 7446-32-4. Email. IUPAC-Gruppe oder Stickstoffgruppe. ID of ANTIMONY Cations by Precipitation Reactions : RELEASE DATE: 16 JULY 1997 : LAST UPDATE: 31-July-98 : VERSION HISTORY: 1.0, 1.1, 1.2 ( Context updates) V2.0 ( Text and formatting update - Sep-2009) INTRODUCTION: This is an account on how to detect Antimony ions in solution by simple precipitation reactions. Tianjing Wu. \[\ce{Sb^{3+}(aq) + 3OH^{-}­(aq) <=> Sb(OH)3(s)}\], \[\ce{Sb(OH)3(s) + OH­^{-}­(aq) <=> Sb(OH)4­^{-}­(aq)}\], \[\ce{Sb(OH)3(s) + 3H^{+}(aq) <=> Sb^{3+}(aq) + 3H2O(l) }\]. Download. Antimony trisulfide (Sb 2 S 3) is found in nature as the crystalline mineral stibnite and the amorphous red mineral metastibnite. Diese lassen sich anschließend vom überschüssigen Antimon(III)-fluorid abdestillieren. However, antimony purification from liquid system is yet poorly documented. Dual Functions of Potassium Antimony(III)‐Tartrate in Tuning Antimony/Carbon Composites for Long‐Life Na‐Ion Batteries. A STUDY OF THE ION EXCHANGE REMOVAL OF ANTIMONY(III) AND ANTIMONY(V) FROM COPPER ELECTROLYTES. Recently, luminescent antimony (III) and bismuth (III) hybrid halide compounds have aroused great research interest. Antimon(III)-oxid (auch Antimontrioxid genannt) ist eine Antimonverbindung mit der Summenformel Sb2O3. Contents. 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